Formation of a supramolecular hyperbranched polymer from self-organization of an AB2 monomer containing a crown ether and two paraquat moieties.

Synthesis and characterization of a luminescence metallosupramolecular hyperbranched polymer.

A luminescence supramolecular hyperbranched polymer is reversibly fabricated by successively adding acid and base to a solution of an AB2 platinum(II) monomer in dichloromethane on the basis of acid-base controllable host-guest recognition of dibenzo[24]crown-8 moieties with dialkylammonium ion centers.

A supramolecular triarm star polymer from a homotritopic tris(crown ether) host and a complementary monotopic paraquat-terminated polystyrene guest by a supramolecular coupling method.

The first supramolecular star polymer based on pseudorotaxane host-guest complexation was prepared from statistical complexation of a homotritopic tris(crown ether) host and monotopic paraquat-terminated polystyrene guest in solution. The formation of this supramolecular star polymer was confirmed by proton NMR characterization and viscosity studies.

Formation of polypseudorotaxane networks by cross-linking the quadruple hydrogen bonded linear supramolecular polymers via bisparaquat molecules.

The creation of novel crown ether-paraquat polypseudorotaxane networks, constructed by bisparaquat monomers threading into the cavity of the crown ether units of linear supramolecular polymers that are formed based on the quadruple hydrogen bonded unit ureidopyrimidinone (Upy) in the concentrated solution, is described.

Formation of Supramolecular Polymers from Homoditopic Molecules Containing Secondary Ammonium Ion and Crown Ether Moieties

Supramolecular polymer nanofibers via electrospinning of a heteroditopic monomer.

Driven by the benzo-21-crown-7/secondary ammonium salt recognition motif, a linear supramolecular polymer was formed from self-organization of a low-molecular-weight self-complementary monomer in chloroform. From this supramolecular polymer, nanofibers were obtained successfully via electrospinning.